Yes, accustom is in the scrabble dictionary

...and is worth 18 points by itself.

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Accustom Definition

verb-transitive

To familiarize, as by constant practice, use, or habit: I have accustomed myself to working long hours.
from The American Heritage Dictionary of the English Language, 4th Edition

verb

To make familiar with something through use or experience.
from Free Scrabble Dictionary

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Top Words by points

Points

accustom

14

2 letter words with ACCUSTOM

Points

am

4

as

2

at

2

ma

4

mo

4

mu

4

om

4

os

2

so

2

ta

2

to

2

um

4

us

2

ut

2

3 letter words with ACCUSTOM

Points

act

5

amu

5

ats

3

cam

7

cat

5

cos

5

cot

5

cum

7

cut

5

mac

7

mas

5

mat

5

moa

5

moc

7

mos

5

mot

5

mus

5

mut

5

oat

3

oca

5

oma

5

oms

5

out

3

sac

5

sat

3

sau

3

soc

5

som

5

sot

3

sou

3

sum

5

tam

5

tao

3

tas

3

tau

3

tom

5

tum

5

ums

5

uta

3

uts

3

4 letter words with ACCUSTOM

Points

acts

6

amus

6

atom

6

auto

4

camo

8

cams

8

cast

6

cats

6

coat

6

coca

8

coma

8

cost

6

cots

6

cuts

6

macs

8

mast

6

mats

6

maut

6

moas

6

moat

6

mocs

8

most

6

mots

6

muso

6

must

6

muts

6

oast

4

oats

4

ocas

6

omas

6

oust

4

outs

4

scam

8

scat

6

scot

6

scum

8

scut

6

smut

6

soca

6

soma

6

stoa

4

stum

6

sumo

6

taco

6

tams

6

taos

4

taus

4

toms

6

tosa

4

tums

6

utas

4

5 letter words with ACCUSTOM

Points

ascot

7

atoms

7

autos

5

camos

9

coact

9

coast

7

coats

7

cocas

9

comas

9

costa

7

mauts

7

moats

7

musca

9

scout

7

scuta

7

stoma

7

sumac

9

tacos

7

6 letter words with ACCUSTOM

Points

accost

10

cactus

10

coacts

10

custom

10

mascot

10

mucosa

10

muscat

10

satcom

10

stucco

10

8 letter words with ACCUSTOM

Points

accustom

14

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