Yes, afire is in the scrabble dictionary

...and is worth 8 points by itself.

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Afire Definition

adverb

Intensely interested.
from The American Heritage Dictionary of the English Language, 4th Edition
On fire.
from The American Heritage Dictionary of the English Language, 4th Edition

adjective or adverb

Being on fire .
from Free Scrabble Dictionary
Being in a state of great excitement or energy .
from Free Scrabble Dictionary

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Top Words by points

Points

feria

8

2 letter words with AFIRE

Points

ai

2

ar

2

ef

5

er

2

re

2

fa

5

fe

5

if

5

ae

2

3 letter words with AFIRE

Points

fir

6

rif

6

ria

3

rei

3

ref

6

rai

3

ire

3

fer

6

air

3

are

3

arf

6

ear

3

era

3

far

6

fie

6

4 letter words with AFIRE

Points

frae

7

fire

7

fiar

7

fear

7

arie

4

fare

7

fair

7

reif

7

rife

7

5 letter words with AFIRE

Points

feria

8

afire

8

Found 35 words in 0.14459 seconds