Yes, aflame is in the scrabble dictionary

...and is worth 13 points by itself.

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Aflame Definition

adverb

Keenly excited and interested.
from The American Heritage Dictionary of the English Language, 4th Edition
On or as if on fire.
from The American Heritage Dictionary of the English Language, 4th Edition

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Top Words by points

Points

aflame

11

2 letter words with AFLAME

Points

ae

2

me

4

ma

4

la

2

fe

5

fa

5

em

4

el

2

ef

5

am

4

al

2

aa

2

3 letter words with AFLAME

Points

ala

3

lam

5

lea

3

fam

8

aal

3

elm

5

elf

6

ale

3

ama

5

mae

5

mel

5

4 letter words with AFLAME

Points

flam

9

leaf

7

lame

6

lama

6

male

6

meal

6

flea

7

alef

7

feal

7

fame

9

alae

4

alme

6

alma

6

alfa

7

5 letter words with AFLAME

Points

fleam

10

flame

10

6 letter words with AFLAME

Points

aflame

11

Found 40 words in 0.18352 seconds