Yes, alone is in the scrabble dictionary

...and is worth 7 points by itself.

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Alone Definition

adjective

Being apart from others; solitary.
from The American Heritage Dictionary of the English Language, 4th Edition
Being without anyone or anything else; only.
from The American Heritage Dictionary of the English Language, 4th Edition
Being without equal; unique.
from The American Heritage Dictionary of the English Language, 4th Edition
Considered separately from all others of the same class.
from The American Heritage Dictionary of the English Language, 4th Edition
Separated from others .
from Free Scrabble Dictionary

adverb

Exclusively; only: The burden of proof rests on the prosecution alone.
from The American Heritage Dictionary of the English Language, 4th Edition
Without help: carried the suitcases alone.
from The American Heritage Dictionary of the English Language, 4th Edition
Without others: sang alone while the choir listened.
from The American Heritage Dictionary of the English Language, 4th Edition
Without aid or support .
from Free Scrabble Dictionary

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Top Words by points

Points

anole

5

2 letter words with ALONE

Points

al

2

an

2

on

2

oe

2

no

2

el

2

en

2

ne

2

na

2

ae

2

la

2

lo

2

3 letter words with ALONE

Points

lea

3

one

3

ole

3

nae

3

eon

3

ane

3

ale

3

4 letter words with ALONE

Points

enol

4

lane

4

lean

4

leno

4

loan

4

lone

4

elan

4

noel

4

aloe

4

aeon

4

olea

4

5 letter words with ALONE

Points

anole

5

alone

5

Found 32 words in 0.13192 seconds