Yes, cannot is in the scrabble dictionary

...and is worth 11 points by itself.

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Cannot Definition

auxiliary-verb

The negative form of can1.
from The American Heritage Dictionary of the English Language, 4th Edition

Can not.
from Free Scrabble Dictionary

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Top Words by points

Points

canton

8

2 letter words with CANNOT

Points

at

2

an

2

no

2

na

2

on

2

ta

2

to

2

3 letter words with CANNOT

Points

tan

3

not

3

nan

3

oat

3

oca

5

tao

3

cot

5

con

5

cat

5

can

5

ton

3

ant

3

act

5

4 letter words with CANNOT

Points

taco

6

nota

4

nona

4

nano

4

conn

6

coat

6

cant

6

anon

4

5 letter words with CANNOT

Points

cotan

7

canto

7

octan

7

canon

7

ancon

7

6 letter words with CANNOT

Points

canton

8

cannot

8

Found 35 words in 0.19532 seconds