Yes, captive is in the scrabble dictionary

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Captive Definition

noun

One held in the grip of a strong emotion or passion.
from The American Heritage Dictionary of the English Language, 4th Edition
One, such as a prisoner of war, who is forcibly confined, subjugated, or enslaved.
from The American Heritage Dictionary of the English Language, 4th Edition

adjective

Enraptured, as by beauty; captivated.
from The American Heritage Dictionary of the English Language, 4th Edition
Held in bondage; enslaved.
from The American Heritage Dictionary of the English Language, 4th Edition
Kept under restraint or control; confined: captive birds.
from The American Heritage Dictionary of the English Language, 4th Edition
Restrained by circumstances that prevent free choice: a captive audience; a captive market.
from The American Heritage Dictionary of the English Language, 4th Edition
Taken and held prisoner, as in war.
from The American Heritage Dictionary of the English Language, 4th Edition

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Top Words by points

Points

captive

14

2 letter words with CAPTIVE

Points

ti

2

pi

4

pe

4

pa

4

it

2

ae

2

et

2

ta

2

te

2

ai

2

at

2

3 letter words with CAPTIVE

Points

vat

6

vie

6

pac

7

via

6

pat

5

pea

5

pec

7

vet

6

pia

5

pic

7

tie

3

pie

5

pit

5

vac

8

tip

5

pet

5

tae

3

tap

5

tav

6

tea

3

tec

5

tic

5

ice

5

ait

3

ape

5

apt

5

ate

3

ave

6

act

5

cap

7

cat

5

cep

7

ace

5

eta

3

eat

3

4 letter words with CAPTIVE

Points

pave

9

etic

6

tepa

6

tape

6

tace

6

epic

8

vita

7

vice

9

pace

8

cape

8

cate

6

cave

9

cite

6

pact

8

vape

9

pita

6

pice

8

pica

8

peat

6

pate

6

5 letter words with CAPTIVE

Points

vatic

10

vitae

8

cavie

10

pieta

7

civet

10

epact

9

evict

10

6 letter words with CAPTIVE

Points

active

11

7 letter words with CAPTIVE

Points

captive

14

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