Yes, chief is in the scrabble dictionary

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Chief Definition

noun

A chief petty officer.
from The American Heritage Dictionary of the English Language, 4th Edition
Heraldry The upper section of a shield.
from The American Heritage Dictionary of the English Language, 4th Edition
Nautical The chief engineer of a ship.
from The American Heritage Dictionary of the English Language, 4th Edition
One who is highest in rank or authority; a leader.
from The American Heritage Dictionary of the English Language, 4th Edition
Slang A boss.
from The American Heritage Dictionary of the English Language, 4th Edition

adverb

Archaic Chiefly.
from The American Heritage Dictionary of the English Language, 4th Edition

adjective

Highest in rank, authority, or office.
from The American Heritage Dictionary of the English Language, 4th Edition
Most important or influential. See Usage Note at absolute.
from The American Heritage Dictionary of the English Language, 4th Edition
Accorded highest rank or office .
from Free Scrabble Dictionary
Of greatest importance or influence .
from Free Scrabble Dictionary

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Top Words by points

Points

fiche

13

2 letter words with CHIEF

Points

ef

5

eh

5

fe

5

if

5

he

5

hi

5

3 letter words with CHIEF

Points

ich

8

ice

5

feh

9

fie

6

chi

8

hic

8

hie

6

4 letter words with CHIEF

Points

fice

9

chef

12

5 letter words with CHIEF

Points

fiche

13

chief

13

Found 17 words in 0.13198 seconds