Yes, chilli is in the scrabble dictionary

...and is worth 13 points by itself.

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Chilli Definition

noun

Variant of chili.

from The American Heritage Dictionary of the English Language, 4th Edition

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Top Words by points	Points
chilli	11

2 letter words with CHILLI	Points
hi	5
li	2

3 letter words with CHILLI	Points
chi	8
hic	8
ich	8
ill	3

4 letter words with CHILLI	Points
hili	7
hill	7
lich	9

5 letter words with CHILLI	Points
chili	10
chill	10
lichi	10

6 letter words with CHILLI	Points
chilli	11

Found 13 words in 0.19563 seconds