Yes, complain is in the scrabble dictionary

...and is worth 19 points by itself.

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Complain Definition

verb-intransitive

To express feelings of pain, dissatisfaction, or resentment.
from The American Heritage Dictionary of the English Language, 4th Edition
To make a formal accusation or bring a formal charge.
from The American Heritage Dictionary of the English Language, 4th Edition

verb

To make a formal accusation or charge.
from Free Scrabble Dictionary
To express grief, pain, or discontent .
from Free Scrabble Dictionary

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Top Words by points

Points

complain

14

2 letter words with COMPLAIN

Points

ai

2

al

2

am

4

an

2

in

2

la

2

li

2

lo

2

ma

4

mi

4

mo

4

na

2

no

2

oi

2

om

4

on

2

op

4

pa

4

pi

4

po

4

3 letter words with COMPLAIN

Points

ail

3

aim

5

ain

3

alp

5

ami

5

amp

7

ani

3

apo

5

cam

7

can

5

cap

7

col

5

con

5

cop

7

imp

7

ion

3

lac

5

lam

5

lap

5

lin

3

lip

5

lop

5

mac

7

man

5

map

7

mic

7

mil

5

moa

5

moc

7

moi

5

mol

5

mon

5

mop

7

nam

5

nap

5

nil

3

nim

5

nip

5

nom

5

oca

5

oil

3

oma

5

opa

5

pac

7

pal

5

pam

7

pan

5

pia

5

pic

7

pin

5

poi

5

pol

5

pom

7

4 letter words with COMPLAIN

Points

amin

6

anil

4

cain

6

calm

8

calo

6

cami

8

camo

8

camp

10

capo

8

ciao

6

cion

6

clam

8

clan

6

clap

8

clip

8

clon

6

clop

8

coal

6

coil

6

coin

6

cola

6

coma

8

comp

10

coni

6

icon

6

laic

6

lain

4

lamp

8

lima

6

limn

6

limo

6

limp

8

lino

4

lion

4

lipa

6

lipo

6

loam

6

loan

4

loca

6

loci

6

loin

4

mail

6

main

6

mano

6

mica

8

milo

6

mina

6

moan

6

moil

6

mola

6

nail

4

naoi

4

nipa

6

noil

4

noma

6

opal

6

pail

6

pain

6

pali

6

palm

8

pial

6

pian

6

pica

8

pima

8

pina

6

pion

6

plan

6

5 letter words with COMPLAIN

Points

aloin

5

amino

7

amnic

9

amnio

7

campi

11

campo

11

capon

9

claim

9

clamp

11

clomp

11

colin

7

comal

9

copal

9

lapin

7

liman

7

limpa

9

linac

7

macon

9

malic

9

manic

9

milpa

9

monic

9

nicol

7

nopal

7

panic

9

piano

7

pical

9

plain

7

plica

9

6 letter words with COMPLAIN

Points

alnico

8

anomic

10

camion

10

caplin

10

copalm

12

lipoma

10

manioc

10

oilcan

8

oilman

8

7 letter words with COMPLAIN

Points

campion

13

complin

13

lampion

11

limacon

11

oilcamp

13

8 letter words with COMPLAIN

Points

complain

14

Found 184 words in 0.41067 seconds