Yes, insure is in the scrabble dictionary

...and is worth 8 points by itself.

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Insure Definition

verb-transitive

To acquire or have insurance for: insured herself against losses; insured his car for theft.
from The American Heritage Dictionary of the English Language, 4th Edition
To make sure, certain, or secure. See Usage Note at assure.
from The American Heritage Dictionary of the English Language, 4th Edition
To provide or arrange insurance for: a company that insures homeowners and businesses.
from The American Heritage Dictionary of the English Language, 4th Edition

verb-intransitive

To buy or sell insurance.
from The American Heritage Dictionary of the English Language, 4th Edition

verb

To provide or obtain on or for.
from Free Scrabble Dictionary
To make certain especially by taking necessary measures and .
from Free Scrabble Dictionary
To contract to give or take insurance.
from Free Scrabble Dictionary

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Top Words by points

Points

rusine

6

2 letter words with INSURE

Points

er

2

en

2

us

2

un

2

si

2

re

2

nu

2

ne

2

es

2

in

2

is

2

3 letter words with INSURE

Points

rue

3

uni

3

uns

3

urn

3

use

3

ens

3

ern

3

sei

3

sen

3

ser

3

sin

3

sir

3

sri

3

run

3

rin

3

res

3

rei

3

ers

3

sue

3

nus

3

sun

3

ire

3

ins

3

4 letter words with INSURE

Points

sure

4

sine

4

rins

4

sire

4

suer

4

ruse

4

runs

4

rune

4

ruin

4

rues

4

rise

4

reis

4

rein

4

unis

4

urns

4

user

4

ires

4

erns

4

5 letter words with INSURE

Points

reins

5

urine

5

siren

5

sieur

5

serin

5

runes

5

ruins

5

risen

5

rinse

5

resin

5

nurse

5

inure

5

6 letter words with INSURE

Points

rusine

6

inures

6

insure

6

urines

6

ursine

6

Found 69 words in 0.17684 seconds