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Yes, iron is playable

...and is worth 5 points.

Found in the following dictionaries

Enable (Words with friends)
SOWPODS (Collins Scrabble Words)
OTCWL2014 (NASPA Word List 2014)
TWL06 (NASPA List 2006)

"Iron" Definition

noun

A harpoon.
A metal appliance with a handle and a weighted flat bottom, used when heated to press wrinkles from fabric.
A silvery-white, lustrous, malleable, ductile, magnetic or magnetizable, metallic element occurring abundantly in combined forms, notably in hematite, limonite, magnetite, and taconite, and used alloyed in a wide range of important structural materials. Atomic number 26; atomic weight 55.845; melting point 1,535°C; boiling point 2,750°C; specific gravity 7.874 (at 20°C); valence 2, 3, 4, 6. See Table at element.
A tonic, pill, or other medication containing iron and taken as a dietary supplement.
An implement made of iron alloy or similar metal, especially a bar heated for use in branding, curling hair, or cauterizing.

phrasal-verb

Iron out To settle through discussion or compromise; work out.

verb-transitive

To fit or clad with iron.
To press and smooth with a heated iron: iron clothes.
To put into irons; fetter.
To remove (creases) by pressing.

verb-intransitive

To iron clothes.

verb

To furnish or cover with iron.
To shackle with .
To smooth with or as if with a heated iron .
To remove (as wrinkles) by .
To smooth or press cloth or clothing with a heated iron.

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