Yes, matron is in the scrabble dictionary

...and is worth 10 points by itself.

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Matron Definition

noun

A married woman or a widow, especially a mother of dignity, mature age, and established social position.
from The American Heritage Dictionary of the English Language, 4th Edition
A woman who acts as a supervisor or monitor in a public institution, such as a school, hospital, or prison.
from The American Heritage Dictionary of the English Language, 4th Edition
A married woman usually marked by dignified maturity or social distinction.
from Free Scrabble Dictionary
A woman who supervises women or children (as in a school or police station).
from Free Scrabble Dictionary
The chief officer in a women's organization.
from Free Scrabble Dictionary

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Top Words by points

Points

matron

8

2 letter words with MATRON

Points

an

2

na

2

no

2

to

2

am

4

om

4

on

2

or

2

mo

4

ma

4

ar

2

at

2

ta

2

3 letter words with MATRON

Points

rot

3

tao

3

nam

5

nom

5

nor

3

not

3

tam

5

ram

5

rom

5

rat

3

oar

3

oat

3

oma

5

ora

3

ort

3

ran

3

mot

5

art

3

aro

3

man

5

mar

5

mat

5

moa

5

mon

5

mor

5

arm

5

ant

3

tor

3

ton

3

tom

5

tar

3

tan

3

4 letter words with MATRON

Points

roan

4

rota

4

tram

6

torn

4

tora

4

taro

4

tarn

4

nota

4

rato

4

atom

6

mano

6

mart

6

moan

6

moat

6

mora

6

morn

6

mort

6

noma

6

norm

6

rant

4

roam

6

5 letter words with MATRON

Points

manor

7

roman

7

amort

7

toman

7

trona

5

6 letter words with MATRON

Points

matron

8

Found 72 words in 0.24396 seconds