Yes, octagon is in the scrabble dictionary

...and is worth 13 points by itself.

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Octagon Definition

noun

A polygon with eight sides and eight angles.
from The American Heritage Dictionary of the English Language, 4th Edition
A polygon of eight angles and eight sides.
from Free Scrabble Dictionary
A plane figure with eight straight sides and eight angles.
from Free Scrabble Dictionary

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Top Words by points

Points

octagon

10

2 letter words with OCTAGON

Points

an

2

go

3

to

2

ag

3

na

2

no

2

ta

2

on

2

at

2

3 letter words with OCTAGON

Points

not

3

noo

3

nog

4

nag

4

oat

3

oca

5

ono

3

tag

4

got

4

goo

4

goa

4

gat

4

gan

4

oot

3

tao

3

act

5

ago

4

ant

3

can

5

cat

5

cog

6

con

5

coo

5

cot

5

too

3

ton

3

tog

4

tan

3

4 letter words with OCTAGON

Points

tong

5

toga

5

toco

6

tang

5

taco

6

toon

4

goon

5

nota

4

goat

5

gnat

5

agon

5

cant

6

coat

6

onto

4

coon

6

coot

6

5 letter words with OCTAGON

Points

conga

8

tonga

6

tango

6

canto

7

cogon

8

congo

8

conto

7

cotan

7

octan

7

7 letter words with OCTAGON

Points

octagon

10

Found 63 words in 0.26063 seconds