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Yes, octet is in the scrabble dictionary

...and is worth 8 points by itself.

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Octet Definition

noun

A group of eight: "A train of heavy wagons rumbled north on the Winnipeg Trail, drawn by octets of oxen” ( Garrison Keillor).
from The American Heritage Dictionary of the English Language, 4th Edition
A set of eight valence electrons in an atom or ion, forming a stable configuration.
from The American Heritage Dictionary of the English Language, 4th Edition
Music A composition for eight voices or eight instruments.
from The American Heritage Dictionary of the English Language, 4th Edition
Music A group of eight singers or eight instrumentalists.
from The American Heritage Dictionary of the English Language, 4th Edition
See octave.
from The American Heritage Dictionary of the English Language, 4th Edition

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Top Words by points

Points
octet

7

2 letter words with OCTET

Points

et

2

oe

2

te

2

to

2

3 letter words with OCTET

Points

cot

5

eco

5

tec

5

tet

3

toe

3

tot

3

4 letter words with OCTET

Points

cote

6

tote

4

5 letter words with OCTET

Points

octet

7

Found 13 words in 0.14584 seconds