Yes, pial is in the scrabble dictionary

...and is worth 8 points by itself.

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Pial Definition

adjective

Of or pertaining to the pia or pia mater.

from the English-language Wiktionary

Of or relating to the pia mater.

from Free Scrabble Dictionary

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Here are some other words you could make with the letters PIAL, you can also
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Top Words by points	Points
lipa	6

2 letter words with PIAL	Points
ai	2
al	2
la	2
li	2
pa	4
pi	4

3 letter words with PIAL	Points
ail	3
alp	5
lap	5
lip	5
pal	5
pia	5

4 letter words with PIAL	Points
lipa	6
pail	6
pali	6
pial	6

Found 16 words in 0.11515 seconds