Yes, pily is in the scrabble dictionary

...and is worth 10 points by itself.

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Pily Definition

adjective

Like pile or wool.
from the GNU version of the Collaborative International Dictionary of English

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Top Words by points

Points

pily

9

2 letter words with PILY

Points

li

2

pi

4

3 letter words with PILY

Points

lip

5

ply

8

yip

8

4 letter words with PILY

Points

pily

9

Found 6 words in 0.12316 seconds