Yes, pina is in the scrabble dictionary

...and is worth 8 points by itself.

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Pina Definition

A cone of silver amalgam prepared for retorting; also, the residuary cone of spongy silver left after the retorting.

from the GNU version of the Collaborative International Dictionary of English

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Top Words by points	Points
pina	6

2 letter words with PINA	Points
an	2
in	2
na	2
ai	2
pa	4
pi	4

3 letter words with PINA	Points
ain	3
ani	3
nap	5
nip	5
pan	5
pia	5
pin	5

4 letter words with PINA	Points
pina	6
pian	6
pain	6
nipa	6

Found 17 words in 0.13136 seconds