Yes, psionic is in the scrabble dictionary

...and is worth 14 points by itself.

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Psionic Definition

adjective

Of or relating to psionics.
from the English-language Wiktionary

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Here are some other words you could make with the letters PSIONIC, you can also
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Top Words by points

Points

psionic

11

2 letter words with PSIONIC

Points

oi

2

so

2

si

2

po

4

pi

4

os

2

op

4

on

2

no

2

is

2

in

2

3 letter words with PSIONIC

Points

son

3

con

5

cop

7

sic

5

sin

3

sip

5

soc

5

psi

5

pos

5

poi

5

pis

5

pin

5

pic

7

cos

5

ops

5

ons

3

cis

5

ins

3

ion

3

nos

3

nip

5

sop

5

4 letter words with PSIONIC

Points

snip

6

icon

6

ions

4

spin

6

pons

6

pois

6

piso

6

pion

6

pins

6

pics

8

cons

6

scop

8

cops

8

nips

6

cion

6

nisi

4

coin

6

coni

6

5 letter words with PSIONIC

Points

scion

7

sonic

7

pisco

9

pions

7

opsin

7

ionic

7

inspo

7

icons

7

coins

7

cions

7

6 letter words with PSIONIC

Points

pionic

10

ionics

8

7 letter words with PSIONIC

Points

psionic

11

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