Yes, psst is in the scrabble dictionary

...and is worth 7 points by itself.

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Psst Definition

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Here are some other words you could make with the letters PSST, you can also
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Top Words by points

Points

psst

6

3 letter words with PSST

Points

pst

5

4 letter words with PSST

Points

psst

6

Found 2 words in 0.12638 seconds