Yes, pye is in the scrabble dictionary

...and is worth 8 points by itself.

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Pye Definition

noun

Archaic spelling of 1 (the pastry food).
from the English-language Wiktionary
Foot.
from the English-language Wiktionary
Pie.
from the English-language Wiktionary

biographical name

Henry James 1745–1813 Eng. poet laureate (1790–1813).
from Free Scrabble Dictionary

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Top Words by points

Points

pye

8

2 letter words with PYE

Points

pe

4

ye

5

3 letter words with PYE

Points

pye

8

yep

8

Found 4 words in 0.14103 seconds