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Yes, pyran is in the scrabble dictionary

...and is worth 11 points by itself.

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Pyran Definition

noun

Either of two isomeric compounds with the formula C5H6O, having a ring of five carbon atoms and one oxygen atom.
from The American Heritage Dictionary of the English Language, 4th Edition
Either of two cyclic compounds CHO that contain five carbon atoms and one oxygen atom in the ring.
from Free Scrabble Dictionary

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Top Words by points

Points
pyran

10

2 letter words with PYRAN

Points

ar

2

ay

5

na

2

ya

5

pa

4

an

2

3 letter words with PYRAN

Points

pry

8

yar

6

yap

8

rya

6

ray

6

rap

5

ran

3

pya

8

pay

8

par

5

pan

5

nay

6

nap

5

any

6

4 letter words with PYRAN

Points

pray

9

nary

7

yarn

7

5 letter words with PYRAN

Points

pyran

10

Found 24 words in 0.14176 seconds