Yes, rimes is in the scrabble dictionary

...and is worth 8 points by itself.

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Rimes Definition

noun

Plural form of rime.

from the English-language Wiktionary

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Here are some other words you could make with the letters RIMES, you can also
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Top Words by points	Points
rimes	7

2 letter words with RIMES	Points
er	2
es	2
em	4
is	2
re	2
si	2
me	4
mi	4

3 letter words with RIMES	Points
mir	5
rim	5
res	3
rem	5
rei	3
sei	3
ser	3
sim	5
sir	3
mis	5
sri	3
ism	5
ire	3
ers	3
ems	5

4 letter words with RIMES	Points
sire	4
semi	6
rise	4
rims	6
rime	6
rems	6
reis	4
mise	6
mirs	6
mire	6
ires	4
emir	6

5 letter words with RIMES	Points
rimes	7
miser	7
mires	7
emirs	7

Found 39 words in 0.13624 seconds