Yes, spier is in the scrabble dictionary

...and is worth 8 points by itself.

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Spier Definition

noun

One who spies; a spy; a scout.

from The Century Dictionary and Cyclopedia

See speer.

from The Century Dictionary and Cyclopedia

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Here are some other words you could make with the letters SPIER, you can also
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Top Words by points	Points
spire	7

2 letter words with SPIER	Points
es	2
is	2
pe	4
pi	4
si	2
er	2
re	2

3 letter words with SPIER	Points
rei	3
sri	3
sir	3
sip	5
ser	3
sei	3
rip	5
res	3
rep	5
ers	3
ire	3
per	5
pes	5
psi	5
pis	5
pie	5

4 letter words with SPIER	Points
ripe	6
sipe	6
ires	4
sire	4
rise	4
rips	6
reps	6
reis	4
peri	6
pier	6
pies	6

5 letter words with SPIER	Points
spire	7
speir	7
spier	7
peris	7
ripes	7
prise	7
pries	7
piers	7

Found 42 words in 0.14382 seconds