Yes, staw is in the scrabble dictionary

...and is worth 7 points by itself.

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Staw Definition

verb-intransitive

To be fixed or set; to stay.

from the GNU version of the Collaborative International Dictionary of English

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Here are some other words you could make with the letters STAW, you can also
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Top Words by points	Points
swat	7

2 letter words with STAW	Points
at	2
aw	5
as	2
ta	2

3 letter words with STAW	Points
tas	3
wat	6
was	6
twa	6
taw	6
saw	6
sat	3
ats	3

4 letter words with STAW	Points
swat	7
staw	7
taws	7
twas	7
wast	7
wats	7

Found 18 words in 0.12134 seconds