Yes, syne is in the scrabble dictionary

...and is worth 7 points by itself.

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Syne Definition

adverb

Afterward; since then; since.
from The American Heritage Dictionary of the English Language, 4th Edition
Before now; ago.
from The American Heritage Dictionary of the English Language, 4th Edition
Thereupon; next.
from The American Heritage Dictionary of the English Language, 4th Edition
Since then .
from Free Scrabble Dictionary

conjunction

Since.
from The American Heritage Dictionary of the English Language, 4th Edition

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Top Words by points

Points

snye

7

2 letter words with SYNE

Points

en

2

es

2

ne

2

ye

5

3 letter words with SYNE

Points

ens

3

sen

3

syn

6

yen

6

yes

6

4 letter words with SYNE

Points

snye

7

syne

7

yens

7

Found 12 words in 0.119 seconds