Yes, than is in the scrabble dictionary

...and is worth 7 points by itself.

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Than Definition

preposition

Usage Problem In comparison or contrast with: could run faster than him; outclassed everyone other than her.
from The American Heritage Dictionary of the English Language, 4th Edition
In comparison with .
from Free Scrabble Dictionary

conjunction

Used after a comparative adjective or adverb to introduce the second element or clause of an unequal comparison: She is a better athlete than I.
from The American Heritage Dictionary of the English Language, 4th Edition
Used to introduce the second element after certain words indicating difference: He draws quite differently than she does.
from The American Heritage Dictionary of the English Language, 4th Edition
When. Used especially after hardly and scarcely: I had scarcely walked in the door than the commotion started.
from The American Heritage Dictionary of the English Language, 4th Edition
Rather than .
from Free Scrabble Dictionary
Other than.
from Free Scrabble Dictionary

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Top Words by points

Points

hant

7

2 letter words with THAN

Points

ah

5

an

2

at

2

ha

5

na

2

ta

2

3 letter words with THAN

Points

ant

3

hat

6

nah

6

nth

6

tan

3

4 letter words with THAN

Points

hant

7

than

7

Found 13 words in 0.10872 seconds