Yes, tzars is in the scrabble dictionary

...and is worth 14 points by itself.

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Tzars Definition

noun

Plural form of tzar.
from the English-language Wiktionary

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Here are some other words you could make with the letters TZARS, you can also
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Top Words by points

Points

tzars

14

2 letter words with TZARS

Points

as

2

at

2

ar

2

za

11

ta

2

3 letter words with TZARS

Points

zas

12

tas

3

tar

3

sat

3

rat

3

ras

3

ats

3

art

3

ars

3

4 letter words with TZARS

Points

rats

4

star

4

arts

4

tars

4

tsar

4

tzar

13

5 letter words with TZARS

Points

tzars

14

Found 21 words in 0.15696 seconds