Yes, union is in the scrabble dictionary

...and is worth 8 points by itself.

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Union Definition

noun

A building housing such facilities.
from The American Heritage Dictionary of the English Language, 4th Edition
A combination of parishes for joint administration of relief for the poor in Great Britain.
from The American Heritage Dictionary of the English Language, 4th Edition
A combination so formed, especially an alliance or confederation of people, parties, or political entities for mutual interest or benefit.
from The American Heritage Dictionary of the English Language, 4th Edition
A coupling device for connecting parts, such as pipes or rods.
from The American Heritage Dictionary of the English Language, 4th Edition
A device on a flag or ensign, occupying the upper inner corner or the entire field, that signifies the union of two or more sovereignties.
from The American Heritage Dictionary of the English Language, 4th Edition

adjective

Of or relating to a labor union or labor union organizing: the union movement; union negotiations.
from The American Heritage Dictionary of the English Language, 4th Edition
Of, relating to, or loyal to the United States of America during the Civil War: a Union soldier.
from The American Heritage Dictionary of the English Language, 4th Edition
Of, relating to, dealing with, or constituting a union.
from Free Scrabble Dictionary
Of, relating to, or being the side favoring the Union in the American Civil War .
from Free Scrabble Dictionary

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Top Words by points

Points

union

5

2 letter words with UNION

Points

in

2

no

2

nu

2

oi

2

on

2

un

2

3 letter words with UNION

Points

inn

3

ion

3

nun

3

uni

3

4 letter words with UNION

Points

noni

4

noun

4

5 letter words with UNION

Points

union

5

Found 13 words in 0.18536 seconds