Yes, unions is in the scrabble dictionary

...and is worth 9 points by itself.

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Unions Definition

noun

Plural form of union.
from the English-language Wiktionary

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Top Words by points

Points

unions

6

2 letter words with UNIONS

Points

is

2

us

2

un

2

so

2

si

2

os

2

on

2

oi

2

nu

2

in

2

no

2

3 letter words with UNIONS

Points

nos

3

uns

3

uni

3

inn

3

sun

3

sou

3

son

3

sin

3

ins

3

ion

3

ons

3

nun

3

nus

3

4 letter words with UNIONS

Points

onus

4

unis

4

noni

4

noun

4

sunn

4

nous

4

nuns

4

ions

4

inns

4

5 letter words with UNIONS

Points

nonis

5

nouns

5

union

5

6 letter words with UNIONS

Points

unions

6

unison

6

Found 38 words in 0.19479 seconds