Yes, vexes is in the scrabble dictionary

...and is worth 16 points by itself.

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Vexes Definition

verb

Third-person singular simple present indicative form of vex.
from the English-language Wiktionary

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Top Words by points

Points

vexes

15

2 letter words with VEXES

Points

es

2

ex

9

3 letter words with VEXES

Points

eve

6

see

3

sev

6

sex

10

vee

6

vex

13

4 letter words with VEXES

Points

eves

7

exes

11

vees

7

5 letter words with VEXES

Points

vexes

15

Found 12 words in 0.14246 seconds