Yes, with is in the scrabble dictionary

...and is worth 9 points by itself.

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With Definition

preposition

According to the experience or practice of: With me, it is a question of priorities.
As a result or consequence of: trembling with fear; sick with the flu.
As well as; in favorable comparison to: She could sing with the best of them.
At the same time as: gets up with the birds.
By the means or agency of: eat with a fork; made us laugh with his jokes.

idiom

In with Informal In league or association with: He is in with the wrong crowd.
With it Informal Interested in and sensitive to the latest styles and trends; up-to-date.
With it Informal Mentally competent.
With it Informal Streetwise and knowing; savvy.

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Top Words by points

Points

whit

10

2 letter words with WITH

Points

hi

5

it

2

ti

2

3 letter words with WITH

Points

hit

6

wit

6

4 letter words with WITH

Points

whit

10

with

10

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